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By Sunil Bhardwaj

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  • Derive an expression for the EMF of Electrode Concentration Cell Reversible to Cations (cell with amalgam electrode). $$\underset {{a}_{1}}{ Cd\left( Hg \right) } | \underset { aq.soln }{ CdS{ O }_{ 4 } } | \underset { { a }_{ 2 } }{ Cd\left( Hg \right) } $$

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  • Derive an expression for the EMF of Electrode Concentration Cell Reversible to Cations (cell with gas electrode).

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  • Derive an expression for the EMF of Electrode Concentration Cell Reversible to Anions (cell with gas electrode). $$ \underset {{P}_{1}}{Pt, {Cl}_{2}\left( g \right) } | \underset { aq.soln }{ NaCl } | \underset { { P }_{ 2 } }{ Cl_{ 2 }\left( g \right) , Pt } $$

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  • EMF of Electrolyte Concentration Cell Reversible to Cations without Transference.

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  • EMF of Electrolyte Concentration Cell Reversible to Anion without Transference.

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