7046 Views
4996 Views
6371 Views
5371 Views
9310 Views
5209 Views
(a) Diatomic molecules with simple harmonic oscillator fails to explain the higher vibrational states. Thus it requires correction.
(b) In harmonic oscillators, the vibrational energy levels go on decreasing, according to experimental results observed. But they are represented by equal spacing.
(c) Over-tones and combination terms are also observed in vibrational spectra. But the harmonic oscillator does not explain this fact. Hence, it is necessary that the diatomic molecules should be considered as anharmonic oscillator.
4104 Views
12280 Views
5091 Views
4448 Views
5261 Views
Apply to join the passionate instructors who share their expertise and knowledge with the world. You'll collaborate with some of the industry's best producers, directors, and editors so that your content is presented in the best possible light..